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Two dimensional correlation spectroscopy applications in vibratioal and optical spectroscopy - Isao N.

Two dimensional correlation spectroscopy applications in vibratioal and optical spectroscopy - Isao N.

Two dimensional correlation spectroscopy applications in vibratioal and optical spectroscopy

Author: Isao N.
Publishers: Wiley publishing
Year of publication: 2004
Number of pages: 312
ISBN 0-471-62391-1
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Download: twodimensionalcorrela2004.pdf

TWO-DIMENSIONAL
CORRELATION SPECTROSCOPY
Applications in Vibrational and Optical Spectroscopy
WILEY
Two-dimensional Correlation
Spectroscopy - Applications in Vibrational and Optical Spectroscopy
Isao Noda
Procter and Gamble, West Chester, OH, USA and
Yukihiro Ozaki
Kwansei-Gakuin University, Sanda, Japan
John Wiley St Sons, Ltd
Two-dimensional Correlation Spectroscopy - Applications in Vibrational and Optical Spectroscopy
Two-dimensional Correlation
Spectroscopy - Applications in Vibrational and Optical Spectroscopy
Isao Noda
Procter and Gamble, West Chester, OH, USA and
Yukihiro Ozaki
Kwansei-Gakuin University, Sanda, Japan
John Wiley St Sons, Ltd
Copyright 2004 John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester,
West Sussex PO19 8SQ, England
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Library of Congress Caialoging-in-Publication Data
Noda, I. (Isao)
Two dimensional correlation spectroscopy : applications in vibrational and optical spectroscopy / Isao Noda and Yukihiro Ozaki. p. cm.
Includes bibliographical references and index.
ISBN 0-471-62391-1 (cloth : alk. paper)
1. Vibrational spectra. 2. Linear free energy relationship. 3. Spectrum analysis. I. Ozaki,
Y. (Yukihiro) II. Title.
QD96.V53N63 2004 539/.6 - dc22
2004009878
British Library Cataloguing in Publication Data
A catalogue record for this book is available from the British Library ISBN 0-471-62391-1
Typeset in 10/12pt Times by Laserwords Private Limited, Chennai, India
Printed and bound in Great Britain by TJ International, Padstow, Cornwall
This book is printed on acid-free paper responsibly manufactured from sustainable forestry
in which at least two trees are planted for each one used for paper production.
Contents
Preface xi
Acknowledgements xiii
1 Introduction 1
1.1 Two-dimensional Spectroscopy 1
1.2 Overview of the Field 3
1.3 Generalized Two-dimensional Correlation 6
1.3.1 Types of Spectroscopic Probes 7
1.3.2 External Perturbations 7
1.4 Heterospectral Correlation 9
1.5 Universal Applicability 10
2 Principle of Two-dimensional Correlation Spectroscopy 15
2.1 Two-dimensional Correlation Spectroscopy 15
2.1.1 General Scheme 15
2.1.2 Type of External Perturbations 16
2.2 Generalized Two-dimensional Correlation 17
2.2.1 Dynamic Spectrum 17
2.2.2 Two-dimensional Correlation Concept 18
2.2.3 Generalized Two-dimensional Correlation Function 19
2.2.4 Heterospectral Correlation 20
2.3 Properties of 2D Correlation Spectra 20
2.3.1 Synchronous 2D Correlation Spectrum 20
2.3.2 Asynchronous 2D Correlation Spectrum 22
2.3.3 Special Cases and Exceptions 24
2.4 Analytical Expressions for Certain 2D Spectra 24
2.4.1 Comparison of Linear Functions 24
2.4.2 2D Spectra Based on Sinusoidal Signals 26
2.4.3 Exponentially Decaying Intensities 28
2.4.4 Distributed Lorentzian Peaks 29
2.4.5 Signals with more Complex Waveforms 30
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