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Indoles - Sundberg R.J.

Sundberg R.J. Indoles - Academic press, 1996. - 95 p.
ISBN 0-12-676945-1
Download (direct link): indoles1996.djvu
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2-(2-Meihylphenyl)-I-(2-irimethylsilyiethoxymethyl) indole............................................100
I-(\ert-Butoxycarbonyl)-2-(4-cyanophenyl)indole..........................................................................100
References ............................................................................................................................................................................................................................................................................100
10.3 Acylation and carboxylation....................................................................................................................................................................................................100
Procedure..............................................................................................................................................................................................................................................................................101
Methyl 5-methoxy-a-oxo-I-(phenylsulfonyl) indole-2-acetate..........................................101
References ............................................................................................................................................................................................................................................................................102
10.4 Introduction of other functional groups..........................................................................................................................................................102
References ............................................................................................................................................................................................................................................................................102
11 Introduction of substituents at C3.............................................................................................................................................................................105
11.1 Alkylation ............................................................................................................................................................................................................................................................................105
Procedures..........................................................................................................................................................................................................................................................................108
3-(2-Propenyl)indol e....................................................................................................................................................................108
Methyl 4-[5-(benzyloxycarbonyl) indol-3-ylJmethyl]-3-methoxybenzoate 108
References ............................................................................................................................................................................................................................................................................109
11.2 Vinylation, arylation and alkynylation..............................................................................................................................................................109
Procedures..........................................................................................................................................................................................................................................................................112
4-Bromo-3-(2~methoxycarbonylethenyl)-!-( 4-meihylphenylsulfony I) indole 112 3-Phenyl-I-(phenylsulfonyl) indole..........................................................................................................................112
References ............................................................................................................................................................................................................................................................................112
11.3 Acylation and carboxylation....................................................................................................................................................................................................113
Procedures..........................................................................................................................................................................................................................................................................115
3-f Cyclopentanecarbonyljindole..................................................................................................................................115
3-Acetyl-I-(phenylsulfonyl)indole ............................................................................................................................115
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