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Indoles - Sundberg R.J.

Sundberg R.J. Indoles - Academic press, 1996. - 95 p.
ISBN 0-12-676945-1
Download (direct link): indoles1996.djvu
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1-Acetyl-2-butyl-5-chloroindole ....................................................................................................................................24
2- (3-oc-Acetoxyandrost-16-en-l 7-yl) indole....................................................................................................24
References ................................................................................................................................................................................................................................................................................24
2.5 Reductive cyclization of o-nitrostyrenes..............................................................................................................................................................24
Procedures ..............................................................................................................................................................................................................................................................................25
Ethyl indole-2-carboxylate..................................................................................................................25
2-Phenylindole......................................................................................................................................................26
References ........................................................................................................................................................................................................................................................................26
X
DETAILED CONTENTS
3 Category 1Л cvcli/ations (| J 27
3.1 Indoles from o-alkylanilides-the Madelung synthesis........................................................................................................27
Procedures ..............................................................................................................................................................................................................................................................................29
2-(tert-Butyl)indule ..................................................................................................................................................................................................................29
2-(4-Phenylbutyl)indule ............................................................................................29
References .............................................................................................................................................................................................................................................................................30
3.2 Indoles from o-acylaniline derivatives ......................................................................................................................................................................30
References .............................................................................................................................................................................................................................................................................32
3.3 Indoles from ojV-diacylanilines..........................................................................................................................................................................................32
Procedure............................................................................................................................................................................................................................................................................32
S-3-Phenyl-2-[N-ftriffuoroacetyl)pyrrolidin-2-yl]indole ........................................................32
References ............................................................................................................................................................................................................................................................................33
4 Category If cyclizations ............................................................................................................................................................^
4.1 Transition metal-catalysed cycli7ation of A?-allyl- and N-propargyl anilines..................35
Procedure................................................................................................................................................................................................................................................................................38
7-Benzyloxy-3-methyl-5-nitroindo!e..........................................................................................................38
References ......................................................................................................................................................................................................................................................................38
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