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Europium - Sinha S.P.

Sinha S.P. Europium - Springer-Verlag, 1967. - 88 p.
Download (direct link): europium1967.djvu
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Curie temperature (6) 33, 34, 45,46 Cyclopentadienyl complex 98
Darken-Gurry plot 42 Degeneracy number 101
1,2-diaminocyclohexane-N,N ,N',N' -tetraacetic acid (DCTA) 91, 94,
95, 96, 97 Dibenzoylmethide (DBM) 88, 89, 132, 133, 134
160
Subject Index
Diborane 49 -%» Didymia 2
Diethylenetriaminepentaacetic acid (DTPA) 91, 95, 97, 127 Diglycolate 82, 83, 96 £}-diketonate 87, 88, 89, 132 —, lewis base adduct 89 4,4'-dimethoxybenzophenone 132 Di -w-butyl phosphoric acid 13 Dipicolinate 82, 96 2,2/-dipyridyl (Dip) 73, 74, 75, 77,
132, 134 Divalent ions, ground state 111 Dy203 57, 58, 59 DyOCl 68 Dysprosia 2
EEDTA 91, 95 EGTA 91, 95 Ekaboron 2
Electronegativity 38, 39, 40, 41 Electronic configuration, Mh 100
--, M2+ 100
--, M3+ 36
--, neutral atom 29
Electrophoresis 19 Electrostatic interaction parameters 101 Energy levels, neutral europium (Eu°, EuII) 107
--, singly ionized europium (Eu+,
Eu I) 109
--, tripositive europium (Eu3+)
118
— —, tripositive rare earths 110 Erbia 2
Er203 57, 58, 59 ErOCl 68
N,Nr-ethylene« liaminediacetic acid (EDDA) 91, 93 Ethylenediamin-NjNjN'.N'-tetra-acetic acid (EDTA) 15, 16, 17,
90, 91, 92, 93, 94, 95, 96, 97, 127 Ethyleneglycol -fris-(2-amino ethyl)
ethertetraacetic acid (EGTA)
91, 95
s-ethylthioglycolate (SETG) 98 Eu+ 34, 108
Eu2+ 32, 33, 49, 65, 96, 109, 125,
126, 129 Eu As 43 EuAs04 49 EuB6 43
EuBOs 66
EuBr2 51, 52
Eu(Br03)3 • 9H20 50, 133
EuC2 43, 44
EuCd6 44
EuCdn 44
EuC12 49, 51, 52
EuCl3 37, 38, 52, 53, 69, 127
EuCl3 • 6H20 53
EuC03 50, 64
Eu2(C03)3 • 2H20 50
EuCr03 60
EuDi.95 44
EuF2 51
EuF3 52
EuFeOs 60
Eu3Fe5012 60
Eu3Ga3012 60
EuGd2S4 46
EuGd2Se4 46
EuGd2Te4 46
EuI2 51, 52, 53
Eulr2 44
EuN 44
Eu(NH2)2 49
Eu(N03)3 57, 127, 128
EuO 64, 66, 67
Eu203 43, 52, 57, 58, 59, 61, 64, 66, 67, 70, 71, 80, 119, 137 Eu304 64, 65, 66 EuoOo • 3Ta205 67 EuOCl 53, 68 EuOF 68
Eu(OH)3 54, 55, 56, 68 EuOOH 55, 68 Eu202S 68, 69 Eu202S04 70 Eu0.5Pa0.5O2 66 EuP04 69 EuS 44, 45 EuSb 43 EuSc03 60 EuSe 45, 97 EuSi2 45 EuSiOs 67 Eu2Si04 66, 67 Eu3Si05 67 Eu4(Si04)3 67 EuS04 50, 69, 70 Eu2(S04)3 69, 70, 127 Eu2Sr04 65 EuTe 46
Subject Index
161
Eu(Terp)Cl3 • H20 76, 126 Eu(Terp)2Cl3 • 4H20 76, 126, 134 Eu2(W04)3 71 Europia 3 Europic halides 52 Europium, coordination compounds, Inorganic 49
—»--, organic ligands 73
—, energy levels 106 —, magnetic properties 33 —, preparation 25 —, properties 26 —, spectroscopic properties 100 —, use and application 135 Europous halides 51 Euxenite 6
Fergusonite 5, 6
/->c? transition 111, 112, 123, 125 Florentium 3 Fluorescence decay 133 —, intensity 127
lifetime 127, 129, 133, 134 —, yield 128
Fluorescence spectra, in solution 127
--, complexes 130
--, glasses 127
--, inorganic crystals 127
Fluoride 24, 51, 52 Formate 77
Formation constant (kn) see Stability constant Fractional crystallization 10, 12 Fractional precipitation 10, 11 Fractional thermal decomposition 10, 12
Gadolina 3 Gadolinite 2, 5, 6
Gadolinium break 48, 83, 88, 95, 112
Gas chromatography 17, 18
Gd3+ 35, 95
Gdlr2 44
Gd2Oa 57, 58, 59
GdOCl 68
Gluconate 86
Glycine 93
Glycolate 81, 82, 83, 84, 85 Glycolic acid 81 Glyoxylate 83, 84 Gold 8
Halide 48, 51, 54
Hexavanadate 73 Holmia 2
Homogeneous precipitation 11 Ho2Oa 57, 58, 59 HoOCl 68 Huttonite 49 Hydroxide 54, 55 a-hydroxyacid 80, 81 N-hydroxyethylethylene-diamine-triacetic acid (HEDTA) 16, 91,
93, 94, 95, 97 X-hydroxyethyliminodiacetic acid (HIMDA) 91, 93, 96 a-hydroxyisobutyrate (HIB) 16,
84, 85
8-hydroxy quinoline sulphonic acid 19
Hypersensitive band 122, 123
-fl-effect 94, 132
— I-effect 82 Illinium 3
Iminodiacetic acid (IMDA) 91, 93, 96
Inorganic compounds 49 Intermetallic compounds 41 Intermolecular sensitization 132 Instability constant (i^inst) 48 Intramolecular energy transfer (IMET) 86, 128, 130, 131, 132, 136 Iodide 51
Ion exchange 10, 14 Ionic radius 29, 30, 54, 71 Iron 8
Isobutyrate (IB) 78, 85 Isotopes 138
Jjj coupling 108
Lactate 84, 85 Lactic acid 16, 81 Lande parameter 101, 102 see also spin-orbit coupling parameter (0
Lanthanide 1, 8, 9 —, contraction 18, 30, 48 —, heavier 1, 54, 85 —, lighter 1, 85 La203 57, 58, 59, 60 LaOCl 68 LaOF 68
11 Sinha, Europium
162
Subject Index
Laser 100, 126, 135, 136 LaSi2 45
Lattice constant 27, 51, 52, 54, 58, 60, 65, 66, 67, 68, 69
--, bromate 50
--, carbonate 50
--, EuB0366
--, EuCl2 52
--, EuCl3 53
--, EuCr03 60
--, EuF3 52
--, EuFe03 60
--, Eu3Fe5012 60
--, Eu3Ga3012 60
--, EuO 64
--, Eu304 65
--, EuOF 68
--, Eu(OH)3 55
--, EuO OH 68
--Eu202S 69
--, Eu203 • 3Ta205 67
--, EuP04 69
--, EuScOa 60
--, Eu2Si04 67
--, EuS04 69
--, Eu2(S04)3 • 8HaO 70
--, Eu2Sr04 67
--, Eu2(W04)3 72
--, LiEuF4 54
--, LiEuOa 67
--, oxides 58
--, oxychlorides 68
--, rare earth metals 27
--, Ru2Eu207 67
LaZnn 44 Lead 8 LiEuF4 54 LiEu02 67
Ligand atoms, affinities 47 Lu203 57, 58, 59
Luminescence spectra 126 (see also fluorescence spectra)
Magnetic behaviour 33 —, moment (fXeff) 33, 36, 76, 99 —, susceptibility (x) 33, 35, 45, 51,
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