Books
in black and white
Main menu
Home About us Share a book
Books
Biology Business Chemistry Computers Culture Economics Fiction Games Guide History Management Mathematical Medicine Mental Fitnes Physics Psychology Scince Sport Technics
Ads

Organic Synthess - McKusick B.C.

McKusick B.C., Boekelheide V., Emmons W.D. Organic Synthess - New York, 1963. - 134 p.
Download (direct link): boekelheide1963.pdf
Previous << 1 .. 31 32 33 34 35 36 < 37 > 38 39 40 41 42 43 .. 49 >> Next

Acetal formation, by azeotropic distillation, 42,1 cyclohexanone diallyl acetal from cy-clohexanone, allyl alcohol, and acetone dimethyl acetal, 42, 34 ACETANILIDE, a,a,a-TRICHLORO-, 40,103 Acetic anhydride, acetylation of glu-conolactone with, 41, 79 acetylation of hexahydrogallic acid with, 42, 63 acetylation of tetraacetylgluconic acid with, 41, 80 in dehydration of maleanilic acid, 41, 94
Acetoacetic acid, tert-butyl ester,
42, 28
o-Acetoacetochloranilide, reaction with potassium amide in ammonia to yield 3-acetyloxindole, 40, 1 Acetone cyanohydrin, conversion to the nitrate, 43, 83 Acetone cyanohydrin nitrate, reagent for nitrating amines to nitra-mines, 43, 83 Acetone dibutyl acetal, 42,1 Acetone dimethyl acetal, reaction with re-butanol, 42, 1 Acetophenone, 2-amino-, hydrochloride, 41, 82 Acetophenone, bromination to 3-bromo-acetophenone, 40, 9 chlorination to 3-chloroacetophenone,
40, 9
Acetophenone, 3-bromo-, 40,7
Acetophenone, 4'-methoxy-2-(^>-methoxyphenyl)-, 40,16 3/9-Acetoxy-5-androstene-1 7 /3-car-boxylic acid, 42, 4 3/3-Acetoxyetienic acid, 42, 4 3|3-Acetoxy-5-pregnen-20-one, conversion to 3y3-acetoxyetienic acid, 42, S
3-Acetyloxindole, 40, 1 Acid chlorides, from acids and chloro-vinylamines, 41, 23 from cyanoacetic acid, 41, S from pentaacetylgluconic acid, 41, 80 Acrylamide, N-benzyl-, 42,16 Acrylonitrile, reaction with benzyl alcohol, 42, 16 Acylation, of enamines by acid halides, 43, 34
of ethyl acetoacetate by y-carbeth-oxybutyryl chloride, 42, 41 Adamantane, 42, 8
Addition, allyllithium to 4-methyl-2-pentanone, 41, 30 allylmagnesium bromide to acrolein, 41,49
dichlorocarbene to dihydropyran, 41,
76
dihalophosphines to 1,3-dienes, 43, 76 Alkylation, of dithiobenzoic acid by chloracetic acid, 42,102 of hexachlorocyclopentadiene by tri-alkylphosphites, 43, 92 of pentane-2,4-dione by methyl iodide, 42, 75
105
106
SUBJECT INDEX
Alkylation, sodium sodiophenylacetate in, 40, 38, 40 Alkyl bromides by action of bromine and mercuric oxide on carboxylic adds, 43, 9 Alkyl chlorides from alcohols and chlo-rovinylamines, 41, 23 S-Alkyl-1,2,3,4,5-pentachlorocyclopen-tadienes from hexachlorocyclo-pentadiene and trialkyl phosphites, 43, 90 Allene, 42,12 addition to maleic anhydride, 43, 27 Allylamine, 2-bromo-, 43, 6 Allyl bromide, in preparation of allyl-magnesium bromide, 41, 49 in preparation of allyltriphenyltin, 41, 31
2-All ylcyclohexanone, Vi, 14 Allyllithium, 41, 30 from allyltin derivatives, 41, 32 reaction with 4-methyl-2-pentanone, 41,30
Allylmagnesium bromide, 41, 49 reaction with acrolein, 41, 49
5 - Allyl-1,2,3,4, S -p en tachlorocy clopen -tadiene, 43, 92 Allyltriphenyltin, 41, 31 reaction with phenyllithium, 41, 30 Aluminum chloride, as catalyst, for isomerization, 42, 9 for nuclear bromination and chlorination of aromatic aldehydes and ketones, 40, 9 as Friedel-Crafts catalyst, 41, 1 Amidation, of aniline with maleic anhydride, 41, 93 of o-toluidine with formic acid, 41,102 N-Amination of amines by hydroxyl-amme-O-sulfonic acid, 43, 1 ^-Aminoacetanilide, oxidation to 4,4'-diaminoazobenzene, 40, 18
2-Aminocyclohexanone, hydrochloride of, 41, 87
2-Aminocyclopentanone, hydrochloride of, 41, 87
l-Amino-2,4-dimethylpyridiniumiodide, 43, 2
1-Amino-2,6-dimethyIpyridmium iodide, 43, 2
2-Amino-4,4-dimethyl-l-tetralone, hydrochloride of, 41, 87
2-Aminoi'Li:ot)t;ne, 40, 5
3-Amino-2-heptanone, hydrochloride of, 41, 87
a-Aminoketones, 41,87
1-Ammo-2-methylpyridinium iodide, 43,
2
a-Aminonitriles from aldehydes and secondary aliphatic amines, 43, 25
2-Amino-2-phenylacetophenone, 41, 87
l-Aminopiperidinium hydrogen oxalate,
43, 2
I-Aminopyeidinium iodide, 43,1
1-Ammoquinolinium iodide, 43,3
2-Amino-l-tetralone, hydrochloride of, 41, 87
4-Amino-2,2,4-trimethylpentane, oxidation to 4-nitro-2,2,4-trimethyl-pentane, 43, 87
l-Amino-2,4,6-trimethylpyridinium iodide, 43, 3 a-Aminovalerophenone, hydrochloride of, 41, 87
Ammonium acetate as catalyst for condensation of furfural with cyano-acetic acid, 40, 47 Ammonium nitrate, explosion hazard of, 43, 48 Aniline, 4,4-azodi-, 40,18 Aniline, reaction with hexachloroace-tone to form a,a,a-trichloro-acetanilide, 40, 103 reaction with maleic anhydride, 41,94 Anisoin, reduction to deoxyanisoin by tin and hydrochloric acid, 40, 16
Anthracene, chlorination by cupric chloride, 43,15 Anthracene, 9-chloro-, 43, IS Anthracene, 9,10-dihydro-, 42,48 Apparatus, for continuous extraction, 43, 52
for Kolbe electrolysis, 41, 25, 33-34, 35-36
SUBJECT INDEX
107
Apparatus, for reactions in liquid ammonia, 40, 1 for solvent stripping, 40, 84 Aromatic aldehydes, nuclear bromina-tion and chlorination of, 40, 9 Aromatic amines, reaction with hexa-chloroacetone to form a,a,a-tri-chloroacetanilides, 40, 104 Aryl tert-butyl ethers from arylmag-nesium halides and tert-butyl perbenzoate, 43, 55 7-Azaindolc-3-carbonitrile, 43, 59
Benzaldehyde, bisulfite addition product of, 43, 25 condensation with 3-benzoylpropionic acid to give a-benzylidene-y-phenyl-MT-butenolide, 43,3 condensation with triphenylcmnamyl-phosphonium chloride to form
Previous << 1 .. 31 32 33 34 35 36 < 37 > 38 39 40 41 42 43 .. 49 >> Next