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The porphyrin handbook - Kadish K.M.

Kadish K.M. The porphyrin handbook - Academic press, 2000. - 368 p.
Download (direct link): kadishsmishgulilard2000.djvu
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reached a point that allows one to build real nanoscopic architectures
with well-defined mutual arrangement between the porphyrinic components
(distances and angles).
The construction principles which govern the assembling of the various
building blocks are relatively well established, although the making of
the most complex ensembles cannot yet be considered as purely
predictable. Nevertheless, the most important aspect of the field, which
to a large extent
40/Noncovalent Multiporphyrin Assemblies
41
will determine its future, is that of the functions and properties of the
assemblies synthesized. Until now, only a small proportion of the
multiporphyrinic systems proposed have been shown to display specific
chemical or physical properties, most of them being related to electron
or energy transfer processes from a photoexcited state. Other functions
can certainly be considered, leading to identification of various
properties for the molecular edifice itself or its supramolecular
assemblies (liquid crystals, films): recognition processes and catalysis,
including enantioselective reactions and information storage at the
molecular level.

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