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The porphyrin handbook - Kadish K.M.

Kadish K.M. The porphyrin handbook - Academic press, 2000. - 368 p.
Download (direct link): kadishsmishgulilard2000.djvu
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Photofrin................................................................
.......... 161
II. Porphyrin-Based
Photosensitizers.........................................................
........................ 161
A. Theoretical
Considerations...........................................................
............................ 161
B. Hematoporphyrin and Protoporphyrin
Analogues................................................................
..... 162
C. Tetraphenylporphyrin (TPP)
Analogues................................................................
............. 163
III. Chlorin-Based
Photosensitizers.........................................................
............................ 164
A. Modification of Chlorophyll
a........................................................................
............ 164
B. Importance of
Lipophilicity............................................................
.......................... 166
C. Chemical Modification of Purpurin-
18.......................................................................
...... 167
IV. Synthetic
Chlorins.................................................................
................................ 170
A. Benzoporphyrin Derivatives
(BPD)....................................................................
............. 1 70
B. Benzochlorins, Naphthochlorins, Purpurins and
Verdins............................................................ 172
C. Tetra(hydroxyphenyl)chlorins
(THPC)...................................................................
........... 177
D. Wc-Dihydroxy- and
Ketochlorins.............................................................
...................... 1 77
E.
Azachlorins..............................................................
........................................ 178
F. Tailor-Made
Chlorins.................................................................
............................ 1 79
G. Chlorins with Ethylidene
Groups...................................................................
............... 179
H.
Spirochlorins............................................................
........................................ 181
I. Direct Synthesis of Chlorins from
Dipyrromethanes..........................................................
...... 181
V. Bacteriochlorin-Based
Photosensitizers.........................................................
.................... 182
A. Naturally Occurring
Bacteriochlorins.........................................................
.................... 182
B. Tolyporphyrin from the Alga Tolypothrix
nodosa...................................................................
183
C. Stable Bacteriochlorins from Rb.
sphaeroides..............................................................
....... 183
VI. Synthetic
Bacteriochlorins.........................................................
.............................. 184
A. Tetrahydrobacteriochlorins and
Isobacteriochlorins......................................................
......... 185
B. Wc-Dihydroxybacteriochlorins and
Isobacteriochlorins......................................................
....... 185
C. Bacteriochlorins via Diels-Alder Reaction
Approach...............................................................
185
D. Wc-Dihydroxybacteriochlorins and their Keto-
Analogues............................................................ 187
E. Effect of Electron Withdrawing Substituents in 0s04 Reactions and
Pinacol-Pinacolone Reaction.................... 190
F.
Benzobacteriochlorins....................................................
........................................ 196
VII. Isomeric
Porphyrins...............................................................
............................... 196
A.
Porphycenes..............................................................
........................................ 196
B. Inverted
Porphyrins...............................................................
............................... 198
VIII. Porphyrin Dimers and Higher
Oligomers................................................................
............ 19B
A. Porphyrin Dimers with Ether, Ester and Carbon-Carbon
Linkages.................................................... 198
B. Chlorin Dimers with Carbon-Carbon
Linkages.................................................................
...... 201
C. Chlorin Dimers with Amide
Linkages.................................................................
.............. 203
IX. Expanded
Porphyrins...............................................................
.................................. 204
Contents
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