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The porphyrin handbook - Kadish K.M.

Kadish K.M. The porphyrin handbook - Academic press, 2000. - 368 p.
Download (direct link): kadishsmishgulilard2000.djvu
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Porphyrins and Metalloporphyrins 46 as Receptor Models in Molecular
Recognition
HISANOBU OCOSHI,a TADASHI MIZUTANI,b TAKASHI HAYASHIC and YASUHISA
KURODAd
aFukui National College of Technology, Geshi, Sabae, Fukui 916-8507,
japan
b Department of Synthetic Chemistry and Biological Chemistry Graduate
School of Engineering, Kyoto University,
Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
c Department of Chemistry and Biochemistry, Graduate School of
Engineering, Kyushu University, Fukuoka 812-8581, Japan d Department of
Polymer Science, Kyoto Institute of Technology, Matsugasaki, Kyoto 606-
0962, Japan
I. New Aspects of Synthesis and Design of Porphyrins for Receptor
Models........................................... 280
A.
Introduction.............................................................
....................................... 280
B. Chemical Modification of Naturally Occurring
Porphyrins......................................................... 280
C. Synthetic Strategy for Multifunctional Porphyrins as Building
Blocks for Receptors.............................. 281
D. Strapped
Porphyrins...............................................................
.............................. 284
E.
Oligoporphyrins..........................................................
....................................... 284
1. Acyclic
Oligoporphyrins..........................................................
........................... 284
2. Dimeric
Porphyrins...............................................................
........................... 284
3. Cyclic Porphyrin
Oligomers................................................................
.................. 285
F. Chiral
Porphyrins...............................................................
................................ 285
1. Extrinsic Chiral Porphyrins and
Metalloporphyrins........................................................
... 285
2. Intrinsic Chiral Porphyrins and
Metalloporphyrins........................................................
... 286
II. Host-Guest Chemistry of Porphyrins in Molecular
Recognition....................................................... 287
A. Recognition of Amines and
Diamines.................................................................
............. 287
B. Amino-Acid Recognition in
Water....................................................................
............. 291
C. Recognition of Amino-Acid Derivatives in Organic
Solvents....................................................... 297
D. Chiral Recognition of Amino-Acid
Derivatives..............................................................
...... 298
E. Alcohols and Sugar
Recognition..............................................................
.................... 300
F. Quinone
Recognition..............................................................
............................... 303
G. DNA
Recognition..............................................................
................................... 304
H. Solvent Effects on Molecular
Recognition..............................................................
.......... 306
I. Thermodynamic Parameters of
Complexation.............................................................
........... 307
J. Combinations of Porphyrin and Other Hosts-Porphyrin-Calixarene,
Porphyrin-Cyclodextrin, Porphyrin-
Steroids.................................................................
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