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Inorganic Syntheses. Volume 33 - Coucouvanis D.

Coucouvanis D. Inorganic Syntheses. Volume 33 - University of Michigan, 2002. - 299 p.
Download (direct link): inorganiksintesis2002.djvu
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then diluted with ethanol (100 mL) and concentrated to - 60 mL. The
bright orange crystals of the title complex are isolated by filtration
and washed with ethanol (4 x 20 mL) and light petroleum ether (20 mL) and
dried in vacuo. Yield: 3.00 g (75% based on [IrCl(-CO)(PPh3b]). A further
small crop of product can be isolated from the filtrate after being
cooled overnight at - 20C. The product can be recrystallized aerobically
from dichloromethane and ethanol to give bright orange crystals.
*
p-tlylthionof miate (Aldrich, 42,061).
Properties
The complex [IrCl(CS)(PPh3)2] is kk indefinitely stable under air as a
solid and shows little sign of decomposition in solution even over a
period of days. The complex shows a characteristically intense
thiocarbonyl absorption in the infrared spectrum (Nujol) at 1328 cm-1.
The 31P-{1H} NMR spectrum (CDC13, 25C) is a singlet at 8.0 ppm. A
molecular ion is observed in the FAB mass spectrum (NBA matrix) at m/z
796 with the complex showing little assignable fragmentation.
References
1. For a review of the chemistry of the title complex and thiocarbonyl
complexes in general, see P. V. Broadhurst, Polyhedron 4, 1801 (1985).
2. M. P. Yagupsky and G. Wilkinson, J. Chem. Soc. A, 2813 (1985).
3. M. Kubota, Inorg. Synth. 19, 206 (1979).
4. T. J. Collins, W. R. Roper, and K. G. Town, J. Organomet. Chem. 121,
C41 (1976).
5. A. F. Hill and J. D. E. T. Wilton-Ely, Organometallics 15, 3791
(1996).
6. K. Vrieze, J. P. Colhnan, . T. Sears, Jr., and M. Kubota, Inorg.
Synth. 11, 101 (1968).
Inorganic Syntheses, Volume 33.
Edited by Dimitri Coucouvaiiis Copyright (c) 2002 John Wiley & Sons, Inc.
ISBNs: 0-471-20825-6 (Hardback); 0-471-22450-2 (Electronic)
CONTRIBUTOR INDEX
Volume 33
Adams, Richard D., 33:119 Amin, Shahid, 33:213 Arnaiz, Francisco J.,
33:203, 204
Baker, Paul K" 33:239 Balzani, Vincenzo, 33:10 Basu, Partha, 33:39
Blanton, Wyndham B., 33:1 Bonavia, Grant, 33:139 Brewer, Karen J., 33:26
Buschmann, Wayne E., 33:83
Campagna, Sebastiano, 33:10 Chappell, Lara L., 33:213 Chen, Qin, 33:52
Chivers, T" 33:196 Chondroudis, Konstantinos, 33:122 Christou, George,
33:61 Clark, Jeff A., 33:26 Claus, Brian L., 33:1 Collins, Terrence J.,
33:1 Comstock, Matthew C., 33:208 Contel, Maria, 33:181 Coucouvanis,
Dimitri, 33:112 Cowan, Jennifer J., 33:18
Delaet, D. L., 33:210 Denti, Gianfranco, 33:10 DiMagno, Stephen G., 33:55
Dorn, Hendrik, 33:230, 234 Dunbar, Kim R., 33:75, 103 Duncan, Dean C.,
33:52
Elding, Lars I., 33:189 Enemark, John H., 33:39 Eppley, Hilary J., 33:61
Fackler, John P., Jr., 33:171 Fedin, Vladimir P., 33:162 Ferreira,
Christina M. P., 33:189
Galarza, Esperanza, 33:171
Garrido, Julian, 33:181 Garzon, Guillermo, 33:171 Gibney, Brian R., 33:70
Girolami, Gregory S., 33:91 Gong, J. K" 33:210 Goodman, Jonathan .,
33:107 Gordon-Wylie, Scott W., 33:1 Gratzel, ., 33:185
Heintz, Robert A., 33:75 Herrmann, Wolfgang A., 33:110 Hill, Anthony F.,
33:206, 244 Hill, Craig L" 33:18, 52 Holmes, Stephen ., 33:91 Horwitz,
Colin P., 33:1
Iovine, Peter ., 33:55
Juris, Alberto, 33:10
Kanatzidis, Mercouri G., 33:122 Kolis, Joseph W" 33:130 Korzenski,
Michael B., 33:130 Kratzer, Roland ., 33:110 Kubiak, C. P., 33:210
Kukushkin, Vadim Yu., 33:189
Laguna, Mariano, 33:181 Laitinen, R. S., 33:196 Lin, Victor S.-Y., 33:55
Longridge, John J., 33:103
Maaninen, A., 33:196 Malinak, Steven ., 33:112 Mazany, Anthony .,
33:171 McKinley, Scott G., 33:91 Meehan, Margaret ., 33:239 Miller, Joel
S., 33:83 Miranda, Mariano J., 33:203 Morrow, Janet R., 33:213 Murray, H.
H., 33:171
247
248 Contributor Index
Nazeeruddin, . K., 33:185
Omary, Manal A. Rawashdeh, 33:171
Pecorado, Vincent L., 33:67, 70 Perrin, Joseph L., 33:119 Pombeiro,
Armando J. L., 33:189 Puntoriero, Fausto, 33:10
Raptis, Raphael, 33:171 Rauchfuss, Thomas B., 33:107 Rawson, Jeremy .,
33:103 Reiner, Richard S., 33:18 Reynolds, Robert ., , 33:112 Richter,
., 33:26 Roesky, Herbert W., 33:230, 234 Rosa, Dell ., 33:112
Sakane, Genta, 33:144, 150 Schutte, Erick J., 33:227 Serrom, Scolastica,
33:10 Shapley, John R., 33:208 Shibahara, Takashi, 33:144, 150 Siivari,
J., 33:196 Silva, Rosalice Mendonfa, 33:199 Smith, Jennifer A., 33:75
Soares, Luis Fernando, 33:199 Staples, Richard J., 33:171 Stemmier, Ann
J., 33:67 Sullivan, B. Patrick, 33:227 Sun, Jui-Sui, 33:103 Sykes,
Geoffrey A., 33:162 Szalay, Paul S., 33:75
Therien, Michael J., 33:55 Thomas, Simon, 33:218
Valek, Michael, 33:39 Van Zyl, Werner E., 33:171 Venturi, Margherita,
33:10
Wang, Suning, 33:171 Weinstock, Ira A., 33:18 Weisgerber, Amy, 33:75
Wilton-Ely, James D. E. ., 33:206, 244 Wright, C. A., 33:210
Young, Charles G., 33:218
Zhang, Xuan, 33:52 Zubieta, Jon, 33:139
SUBJECT INDEX
Names used in this Subject Index are based upon IUPAC Nomenclature of
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